1种提高变压器UHF局部放电信号时延精度的统计方法

通过测量变压器局放信号到达UHF传感器阵列各个阵元的时间延迟来进行PD定位在理论上是可以实现的。电磁波在空气中的传播速率是30 cm/ns,所以解决UHF信号被UHF传感器阵列检测到的时间延迟问题是实现PD精确定位的1个关键。本文提出了1种数学方法:互相关—移位—平均算法,这种算法可以通过增加信噪比和降低随机PD带来的分散性来提高UHF信号时延估计的精度。通过对试验数据的验证,显示这种方法在一些情况下可以将时延精度提高到数十个ps,同时将PD定位精度提高到几个厘变。     

无需特征分解的快速谱聚类算法

为了解决样本数较大时，传统谱聚类算法执行特征分解消耗时间过大的问题，提出了一种无需特征分解的快速谱聚类算法，通过乘法更新迭代来降低时间开销。首先，利用Nyström方法进行随机采样，建立了采样矩阵和原始矩阵之间的关系；其次，基于乘法更新原理实现矩阵指示器矩阵的迭代更新；最后，在理论上对所设计算法进行了正确性和收敛性分析。在广泛使用的五个真实数据集和三个人工合成数据集上进行测试。实验结果表明，在真实数据集上，所提算法的标准互信息（NMI）平均值为0.45，与k-means聚类算法相比提高了12.50%；运行时间为61.73 s，与传统谱聚类算法相比减少了61.13%；而且表现性能优于层次聚类算法，验证了该算法的有效性。     

融合感知损失的单幅雾霾图像深度估计

针对雾霾情况下室内外图像深度难以估计的问题,提出了融合感知损失函数的单幅雾霾图像深度估计方法.首先采用双尺度网络模型对雾霾图像进行粗提取,再结合底层特征进行局部细化;然后在上采样阶段使用多卷积核上采样方法,得到雾霾图像的预测深度图;最后将像素级损失函数与感知损失函数结合构造新的复合损失函数,对网络进行训练.在室内NYU...     

Sb对ZA27合金尺寸稳定性及耐磨性的影响

通过对Zn+Sb二元及ZA27+Sb多元锌基合金的试验数据检测、分析表明:Sb在ZA27合金中与Al形成AlSb化合物相,减少了富Al的α相数量,Sb可钝化α枝晶.Sb的加入提高了合金的尺寸稳定性和耐磨性.含0.5%Sb时,使ZA27合金的磨损量减少59%,在含1.0%Sb时,ZA27合金的尺寸稳定性提高了81%.Sb对ZA27合金韧性产生不利影响.     

Composites of Ni-MOF and polyaniline hydrogel for carbon monoxide resistant excellent catalysts of ethanol oxidation reaction

EOR is a semi-reaction of direct ethanol fuel cells (DEFCs), and determines the performance of the DEFCs. Therefore, it is very important for EOR to rationally design an electrocatalyst with excellent activity, stability and CO-resistance. Based on this, we report the synthesis of MOF based composite catalysts by a facile method, which is formed by combining polyaniline hydrogel (PANH) with MOF 1 and carbon cloth (CC). At the same time, the structures of the composites were characterized by XRD, SEM and XPS. Under the optimum conditions, the j value for EOR is 107 mA cm^?2 under alkaline conditions at 0.6 V, which indicates that composite 2 has excellent catalytic activity for EOR, and is superior to that of the previously reported nickel-based catalysts for EOR. The Tafel slope and the exchange current density of composite 2 are 88.9 mV dec^?1 and 1.95 × 10^?5 A cm^?2 respectively. In addition, the j value of composite 2 was 65% of the original value after 1000 CV cycles. However, when the electrolyte was changed into the original one (1 M KOH + 1 M EtOH), the j value returned to 74% of the original value. Based on the excellent electrocatalytic performance, good stability and anti-CO poisoning, composite 2 is expected to be an economic, efficient and CO poisoning resistant electrocatalyst for EOR.     

The first carbamoyl–carboxylate complex of transition metals: Synthesis and structure of {(OC4H8NH)[OC4H8NC(O)]Pd}2(μ-CMe3CO2)2

Reactions of palladium(I) carbonyl carboxylate complexes [Pd(μ-CO)(μ-RCO₂)]_n with secondary amines on the example of morpholine were studied. It was found that intramolecular carbonylation of amine in coordination sphere of polynuclear palladium species proceeds and binuclear palladium carbamoyl complex {(OC₄H₈NH)[OC₄H₈NC(O)]Pd}₂(μ-RCO₂)₂ forms as a result. This is the first structurally characterized carbamoyl–carboxylate complex of transition metals. Also it was shown that morpholine itself and carboxylate-anions act as proton acceptors in the reaction of carbonylation of morpholine by coordinated CO.     

传统山西老陈醋熏醅工艺过程风味物质及功能活性成分的变化

通过对山西老陈醋熏醅过程中理化指标、风味物质及功能活性成分的测定,分析讨论其变化规律。结果表明,熏醅温度呈现上升趋势,水分含量和pH值呈下降趋势,可溶性固形物、还原糖和氨基酸态氮呈现先上升后下降的趋势,总酸和不挥发酸呈现上升趋势。有机酸总量呈现先下降后上升再下降的趋势,于第4天达到最大值3.35 g/100 g。熏醅的挥发性香气成分共检测出64种,其中31种酯类、6种醇类、5种酸类、10种醛类、3种酚类及9种其他物质。多酚呈现先下降后上升的趋势,熏醅第5天最高为533.06 μg/mL;总黄酮、乙偶姻和川芎嗪的含量呈现上升趋势,第5天达到最大值,分别为627.42 μg/mL、1.06 mg/mL、53.64 μg/mL。     

山西老陈醋醋醅中醋酸菌的分离、ERIC分型及发酵特性研究

通过传统微生物培养分离手段从山西老陈醋醋醅中分离醋酸菌,采用形态学观察及分子生物学技术对其进行鉴定,并对分离菌株进行肠杆菌基因间保守重复序列（ERIC）分型及发酵特性研究。结果表明,共分离筛选出20株醋酸菌,经鉴定18株为巴氏醋杆菌（Acetobacter pasteurianus）,2株为醋化醋杆菌（Acetobacter aceti）。经ERIC分型,18株巴氏醋杆菌属于5个分型（Ⅰ～Ⅴ型）,2株醋化醋杆菌属于2个分型（Ⅰ和Ⅱ型）。经发酵特性研究,巴氏醋杆菌、醋化醋杆菌中Ⅱ型菌株的温度耐受性均优于Ⅰ型;巴氏醋杆菌Ⅰ型菌株产酸、产乙偶姻能力优于其他型的菌株。在此基础上,筛选出的1株性能优良的菌株,为巴氏醋杆菌SAV-CP 1884,其可耐受高温45 ℃、酒精度10%vol及pH 3,乙酸产量高达9.87 g/L、乙偶姻产量为0.86 mg/mL。     

空间电荷对油纸绝缘击穿和沿面闪络的影响

换流变压器是直流输电工程的核心设备之一,其结构和工作状况比传统交流变压器更为复杂,需要对其绝缘系统进行更深入的研究.本文针对换流变压器的特点,设计了相应的试验装置,对油纸绝缘中的体击穿和沿面闪络进行了试验研究.本文实现了变压器油纸绝缘空间电荷的测量,根据空间电荷的实测结果对油纸绝缘系统中极性反转现象进行了探讨,对直流电...     

Fast pyrolysis of date palm biomass using Py-GCMS

Pyrolysis of Date Palm Petiole (DPP) and Date Palm Seed (DPS) biomass was conducted by fast pyrolysis and on-line analysis of the outlet stream by gas chromatography connected to mass spectrometry (Py-GCMS) at different temperatures (450, 500 and 600 °C) in order to study the effect of this variable on the product distribution. The concentration of the components in the volatile stream (bio-oil and non-condensable gases) was greatly influenced by temperature and, to a minor extent, by the content of the biomass components (cellulose, hemicellulose and lignin). The most abundant compound families quantified are acids, anhydrosugars, ketones, furans and phenols. The most abundant compound identified was levoglucosan, which is mainly derived from the degradation of cellulose, with its relative content being as high as 18.3% for DPS pyrolysis at 450 °C and considerably lower for DPP pyrolysis (12.2%). The relative content of acetic acid was as higher as 10.2% at 450 °C for DPP pyrolysis. The knowledge of product composition is crucial for the development of large scale fast pyrolysis units for the valorization of these Tunisian agricultural wastes.